Aligned CNT-based Microstructures and Nano-engineered Composite Macrostructures

  • Authors: B. L. Wardle, S. Wicks, S. Buschhorn, R. Li, D. Handlin, N. Lachman, I. Stein, D. Lewis, W. Wang, P. Florin, M. Devoe, H. Vincent, H. Jethani, E. Parsons
  • Sponsorship: NECST Consortium, NSF, AFOSR, ONR, Army Research Office/Institute for Soldier Nanotechnologies , NASA NSTRF Fellows Program, MIT’s Linda and Richard (1958) Hardy Fellowship

Carbon nanotube (CNT) composites are promising new materials for structural applications thanks to their mechanical and multifunctional properties. We have undertaken a significant experimentally based program to understand both microstructures of aligned-CNT nanocomposites and nano-engineered advanced composite macrostructures hybridized with aligned CNTs.

Aligned nanocomposites are fabricated by mechanical densification and polymer wetting of aligned CNT forests[1]. Polymer wetting is driven by capillary forces that arise upon contact of the polymer with the nanostructured CNT forest[2],[3], the rate of which depends on properties of the CNT forest (e.g., volume fraction) and the polymer (viscosity, contact angle, etc.). Here the polymer is typically an unmodified aerospace-grade epoxy. CNT forests are grown to mm-heights on 1-cm2 Si substrates using a modified chemical vapor deposition process. Following growth, the forests are released from the substrate and can be handled and infiltrated. The volume fraction of the as-grown CNT forests is about 1%; however, the distance between the CNTs (and thus the volume fraction of the forest) can be varied by applying a compressive force along the two axes of the plane of the forest to give volume fractions of CNTs exceeding 20% (see Figure 1a). Variable-volume fraction-aligned CNT nanocomposites were characterized using optical, scanning electron (SEM), and transmission electron (TEM) microscopy to analyze dispersion and alignment of CNTs as well as overall morphology. Extensive mechanical property testing is underway, including 3D constitutive relations and fracture toughness.

Nano-engineered composite macrostructures hybridized with aligned CNTs are prepared by placing long (>20 μm) aligned CNTs at the interface of advanced composite plies as reinforcement in the through-thickness axis of the laminate (see Figure 2). Three fabrication routes were developed: transplantation of CNT forests onto pre-impregnated plies[4] (the “nano-stitch” method), placement of detached CNT forests between two fabrics followed by subsequent infusion of matrix, and in-situ growth of aligned CNTs onto the surface of ceramic fibers followed by infusion or hand-layup[5][6][7]. Aligned CNTs are observed at the composite ply interfaces and give rise to significant improvement in interlaminar strength, toughness, and electrical properties. Extension of the CNT-based architectures to ceramic-matrix composites and towards multifunctional capabilities including structural health monitoring and deicing is underway.

  1. B. L. Wardle, D. S. Saito, E. J. Garcia, A. J. Hart and R. Guzman de Villoria, “Fabrication and characterization of ultra-high volume fraction aligned carbon-nanotube-polymer composites,” Advanced Materials, vol. 20, pp. 2707-2714, 2008. [↩]
  2. H. Cebeci, R. Guzman de Villoria, A. John Hart, and B. L. Wardle, “Multifunctional properties of high volume fraction aligned carbon nanotube polymer composites with controlled morphology,” Composites Science and Technology vol. 69, no 15-16, pp. 2649-2656, 2009. [↩]
  3. E. J. García, A. J. Hart, B. L. Wardle, and A. H. Slocum, “Fabrication and nanocompression testing of aligned carbon-nanotube-polymer nanocomposites,” Advanced Materials, vol. 19, pp. 2151-2156, 2007. [↩]
  4. E. J. García, B. L. Wardle, and A. J. Hart, “Joining prepreg composite interfaces with aligned carbon nanotubes,” Composites Part A, vol. 39, pp. 1065-1070, 2008. [↩]
  5. N. Lachman, E. Wiesel, R. Guzmán de Villoria, B.L. Wardle, and H. D. Wagner, “Interfacial Load Transfer in Carbon Nanotube/Ceramic Microfiber Hybrid Composites,” Composites Science and Technology, Vol. 72, No. 12, July 2012, pp. 1416-1422. [↩]
  6. S. S. Wicks, R. Guzmán de Villoria, and B. L. Wardle, “Interlaminar and intralaminar reinforcement of composite laminates with aligned carbon nanotubes,” Composites Science and Technology, vol. 70, pp. 20–28, 2010. [↩]
  7. S. S. Wicks and B. L. Wardle, “Interlaminar Fracture Toughness of Laminated Composites Reinforced with Aligned Nanoscale Mechanisms at the Macro, Micro, and Nano Scales,” 53rd AIAA SDM Conference, Boston, MA, April 8-11, 2013. [↩]

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