
Unit 10: Energy
Schedule
Lecture 
Tuesday, Apr 29, 2003, 12:00 PM 
Room 37212 
Recitation 
Thursday, May 1, 2003, 12:00 PM 
Room 37212

Problem Set 
Posted Friday, Apr 25, 2003 
Due Friday, May 2, 2003 
Solutions 
Posted Friday, May 2, 2003 

Lecture Handouts
Students who for any reason did not receive these items can pick up a copy in
Room 38344. Most of this material is also available on the 6.050J/2.110J Web site
http://mtlsites.mit.edu/Courses/6.050.
Reading Assignment
Resources
Technical
Seminal papers on the Principle of Maximum Entropy by
Edwin T. Jaynes (July 5, 1922  April 30, 1998):
 Jaynes, E. T., "Information Theory and Statistical Mechanics," Physical
Review, vol. 106, no. 4, pp. 620630; May 15, 1957.
PDF (2.2 MB),
PS (2.6 MB).
This paper started the use of the Principle of
Maximum Entropy in physics
 Jaynes, E. T., "Information Theory and Statistical Mechanics. II," Physical
Review, vol. 108, no. 2, pp. 171190; October 15, 1957.
PDF (2.2 MB),
PS (2.6 MB).
Continuation of the previous reference
 The philosophy of assuming maximum uncertainty is discussed in Chapter 3 of
M. Tribus, "Thermostatics and Thermodynamics," D. Van Nostrand Co, Inc.,
Princeton, NJ; 1961
 Another good explanation, in terms of estimating probabilities of an unfair
die is in E. T. Jaynes, "Information Theory and Statistical Mechanics," pp. 181218 in
"Statistical Physics," Brandeis Summer Institute 1962, W. A. Benjamin, Inc., New York,
NY; 1963. PDF,
PS
 Personal history by Jaynes, Edwin T. Jaynes, "Where Do We Stand on Maximum Entropy?,"
pp. 15118,
in "The Maximum Entropy Formalism," Raphael D. Levine and Myron Tribus, editors, The MIT
Press, Cambridge, MA; 1979.
PDF,
PS
Historical
 JosephLouis Lagrange
biography
 Biography of Ludwig Boltzmann, Austrian physicist, 18441906, who was a pioneer
in thermodynamics and entropy, is Carlo Cercignani, "Ludwig Boltzmann, The Man Who
Trusted Atoms," Oxford University Press, Oxford, UK; 1998.
 On Boltzmann's tombstone
is the formula for entropy "S = k log W"
 Ludwig Boltzmann
biography
 Another Ludwig Boltzmann
biography
 History of the twisted and convoluted development of the difficult concept of
entropy, C. Truesdell, "The Tragicomical History of Thermodynamics,
1822  1854," SpringerVerlag, Berlin; 1980. Professor Truesdell
died January 14, 2000 at the age of 80. He retired from the faculty at
Johns Hopkins University in 1989.
 Edwin T. Jaynes biography,
photograph,
bibliography
Books
There are many textbooks on thermodynamics and energy conversion.
 R. Silbey and R. Alberty, "Physical Chemistry," Wiley; 2001. These
authors are from MIT. Alberty was formerly Dean of Science, and Silbey
is now Dean of Science. It's amazing that anyone can be a Dean and still
keep up with science.
 Typical excellent book in a traditional style, Mark W. Zemansky, "Heat
and Thermodynamics," McGrawHill Book Company, Inc., New York, NY; Third
Edition, 1951, or earlier editions starting in 1937. This book does not
mention information, and starts with assumed knowledge about temperature,
pressure, and volume. Suitable for advanced undergraduates.
 Introductory book, used for sophomores, covering classical thermodynamics
(no information), H. C. Van Ness, "Understanding Thermodynamics," Dover
Publications, New York, NY; 1969. Succinct and carefully crafted treatment.
 Book covering both equilibrium and irreversible thermodynamics,
Herbert B. Callen, "Thermodynamics," John Wiley and Sons, Inc., New York
NY; 1962.
 Careful treatment of classical thermodynamics (no mention of information)
with emphasis on the mathematical formalism, C. Truesdell, "Rational
Thermodynamics," McGrawHill Book Company, New York, NY; 1969. Suitable
for graduate courses, for those with some prior exposure to thermodynamics.
 Textbook developed at MIT in energy conversion (no thermodynamics),
David C. White and Herbert H. Woodson, "Electromechanical Energy Conversion,"
John Wiley and Sons, Inc., New York, NY; 1959.
 An early textbook to use the Principle of Maximum Entropy as an approach
to thermodynamics is M. Tribus, "Thermostatics and Thermodynamics," D. Van
Nostrand Co, Inc., Princeton, NJ; 1961
Help Wanted
6.050J/2.110J students: be the first to suggest a resource, for example a useful Web
site or a good book or article, to add to the list above. If your suggestion is
accepted by the 6.050J/2.110J staff, you will get a $5 icecream gift certificate.
Send your suggestion by email during Spring 2003 to 6.050staff at mit.edu.
