{"id":1205,"date":"2013-07-25T18:26:59","date_gmt":"2013-07-25T18:26:59","guid":{"rendered":"https:\/\/mtlsites.mit.edu\/annual_reports\/2013\/?p=1205"},"modified":"2013-07-25T18:26:59","modified_gmt":"2013-07-25T18:26:59","slug":"materials-and-structures-for-li-air-batteries","status":"publish","type":"post","link":"https:\/\/mtlsites.mit.edu\/annual_reports\/2013\/materials-and-structures-for-li-air-batteries\/","title":{"rendered":"Materials and Structures for Li-air Batteries"},"content":{"rendered":"

Lithium-air batteries hold promise for the next generation of electric vehicles and other applications. By reacting oxygen directly with lithium ions to form Li2<\/sub>O2<\/sub> on discharge, these batteries can achieve energy densities 3-5 times higher than current lithium-ion batteries[1<\/a>]<\/sup>. However, a number of challenges exist for implementation, including poor rate capability, poor cyclability, high overpotentials upon charging, and electrode and electrolyte instability[2<\/a>]<\/sup>. We seek to address these issues by developing new electrode materials and architectures.<\/p>\n

Aligned arrays of carbon nanotubes and nanofibers (CNT\/CNFs) provide ideal conducting scaffolds for growth of Li2<\/sub>O2<\/sub> particles, while the CNT\/Fs themselves are low in mass and occupy a small volume fraction of the discharged electrode.\u00a0 We have grown aligned CNFs 5-10 nm in diameter on oxidized silicon substrates and de-laminated them in the form of cohesive carpets.\u00a0 These free-standing conducting carpets were then placed directly into lithium-air cells. We observed near-ideal gravimetric capacities (Figure 1) and high volumetric energy capacities.\u00a0 Control of particle morphology is critical for the high volumetric capacities needed for most applications. Two distinct types of particle morphologies were observed upon discharge, depending on the rate and depth of discharge[3<\/a>]<\/sup>. At low charge rates or high depths of discharge, we observe the formation of large toroid particles. At high rates of discharge, we observe the formation of copious small particles (Figure 2). From x-ray diffraction and selected area electron diffraction, we determined that these are Li2<\/sub>O2 <\/sub>particles with predominantly (0001) surfaces[3<\/a>]<\/sup>.<\/p>\n

Additionally, we have studied the stability of these carbon nanotube electrodes in a lithium-air cell[4<\/a>]<\/sup>. We observed higher charging overpotentials as the cycle number increased. Using X-ray absorption near edge spectroscopy, we determined that Li2<\/sub>CO3<\/sub> formed in increasing amounts upon cycling at the interface between lithium peroxide and the carbon nanotube [4]. We attribute poor cycling performance and higher charge overpotentials to this Li2<\/sub>CO3<\/sub> formation, possibly due to reaction of Li2<\/sub>O2<\/sub> with the CNTs.\u00a0 We are currently carrying out research to address this issue.<\/p>\n\n\t\t